boiler feed water silica limit

This value will limit the silica content of the steam to 0.25 ppm as a function of selective. The suggested limits for spray water quality are ; 30 ppb (pg/l) TDS maximum, 1 0 ppb (pg/l) sodium as Na maximum, 20 ppb (pg/l) silica as Si02 maximum, and essentially oxygen free. The boiler water alkalinity builder also raises the feed water pH which helps to protect the hot well, feed line and flue gas economisers from acid corrosion. 3.3.5 Make-up water … The deposition is mainly depends on the silica percentage in boiler feed water . In the Midwest, we most commonly find calcium, magnesium, and silica. This ensures that free carbon dioxide within the system becomes ‘fixed’. 5 Heat recovery steam generator (HRSG) − a boiler that has as It is not affected by boiler design. 39. This refers to soluble silica content and not to the silica that may be present in the suspended matter. But when the turbine is becomes foluled with compounds that are not water soluble (including silica), water washing rarly restores capacity. These values are exclusive of silica. This can be written as: Example 3.12.3. Boiler Water Treatment Chemical Guidelines—Part Il continued Because of the associated corrosion problems, chelants are not the preferred treatment choice. What is the recommended Hydrazine residual in feed water? NS. Each boiler system has its own limit of Total Dissolved Solids (TDS) in the feed water and the boiler. Water quality of condensate water, feed-water and boiler water Its presence is highly objectionable as it forms a very hard scale in boilers and forms insoluble deposits on turbine blades. ... 3-7 shows suggested limits. A Simple boiler is a closed vessel which is used for heating fluid, mainly water or converting it to steam. High pH in the boiler water will reduce silica carryover from the boiler water. Silica in deionized water can easily be reduced to 20-50 ppb. Some feed water treatment chemicals, such as chelants, if not properly applied, can corrode feed water piping, control valves, and even the boiler internals. 2�c�Dxaw�X�>�ɞ����T�4�b���zߩ·Λ���j���¡&�����&�ԝu�v�t�F��� The proper boiler water silica level necessary to maintain less than 0.02 ppm silica in the steam is shown in Figure 18-4. %%EOF RE: Chloride level in Boiler feed water EdStainless (Materials) 6 Mar 19 14:57 15 0 obj <> endobj The chemical factors which limit the boiler water cycles of concentration are Suspended solids (Total Hardness) ... Silica 6 0 % Condensate 50 Basic Boiler Calculations. If copper fed lines or heaters are used, restrict the feed water pH to a maximum of 9.2. Boiler deposits result from hardness salts, metallic oxides, silica and a number of other feed water contaminants that can enter the system. All water absorbs gas from the surrounding atmosphere and should be deaerated, or in some cases, run through a good hot water return tank. limit in the condensate pump discharge and the 5 to 10 ppb range in the feedwater outlined above. Steam water separator Boiler water returned to feed tank May include economiser and superheater. Source: Idustrial water conditioning, Betz Dearborn, 1991. Silica from CW is another damaging factor as it deposits on turbine. Set this limit with a water chemistry supplier. 3.3.4 Rusty water in the boiler gage glass is a sure sign of acid corrosion in the boiler feedwater/condesate system or in the boiler itself. WATER TREATMENT BOILER WATER TREATMENT where the silica content is high, or if feed water is taken from cement washed tanks. On the right: Effect of pressure and boiler water pH on the volatility of silica. Silica is not the only mineral that can cause this type of damage to your machinery. Improper and nonexistent feedwater treatment is the major factor causing boiler failure, which ultimately results in boiler down time and costly repairs. The feed water is from the river, I guess that is why the water in the boiler system has some amount of Chloride and it is up to 1500 ppm. The silica concentration is distributed between the water and vapour phases in a boiler. Power generation requires vast quantities of water … Silica, in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. ... the limits … The effect of the pH becomes greater as higer pH values (from 11.3 to 12.1). 38.What is the minimum recommended silica content for feed water and boiler water? In industrial boilers, it is cost prohibitive to eliminate all forms of contaminants in a When a turbine becomes fouled with water soluble salts of boiler water carryover or attemperating water contamination, turbine capacity can often be restored by water washing. By Jon Penn, ABB Inc. Keeping key boiler water and steam contaminants in check can help to ensure a safe and efficient process. Table 3-7. Allowable. Monitor the steam because: •Precipitation of silica forms silicate deposits on the cold end of the turbine that are not water soluble and are very difficult to remove. Table 3-13. NS. You will need to take into consideration your water, your plant, and the chemical The suggested limits for spray water quality are 30 ppb (pg/l) TDS maximum, 1 0 ppb (pg/l) sodium as Na maximum, 20 ppb (pg/l) silica as Si02 maximum, and essentially oxygen free. Silica scales are tipically very hard, glassy haderent, and difficult to remove. 3. Why does steam NS. Boiler Pressure. Internal treatment: Treatment of the boiler feed water, boiler water, steam, or condensate with corrective chemicals. Silica needs to be controlled at DM plant also. A boiler water sample has an unneutralised conductivity of 5 000 μS/cm at 25°C. This can be gained through external treatment equipment for make up water or monitorning and controlling the condensate contmination. Boiler Water Boiler water returned to the feed system by methods 2 and 3 does not reduce the dissolved solids in the boiler, and must not be accounted as part of the blowdown for deconcentration From: The Efficient Use of Energy (Second Edition), 1982 This ratio depends on water pressure and boiler water pH as shown in the picture on the right. 1.1.1 The requirements prescribed are for boilers operating at pressures above 5.9 MN/m9 ( 60 kg/cm2) during normal operation of the unit with Silica. High pH in the boiler water will reduce silica carryover from the boiler water. Article 213-1. Expressed as equivalent calcium carbonate in PPM. h�bbd```b``��)`v$��3�@$�)�����e`�� ��.�d�f�� "M~�H�E@�����b�\����-� �#��� $��A�L�A",�`���T^R��,A�$���A�$���68"u?�H-�� ��P����#@[���v'�#�30Y0 �l � A 3-2.8.5.2. Depending on the natural feed water alkalinity, it is often necessary to add an alkalinity builder in order to establish the correct boiler water chemistry to prevent corrosion and scale formation. Silica measurements are required at this point, principally to confirm that the maximum level of silica permissible in the boiler is not exceeded. For most dissolved solids found in boiler water, it is negligible by comparison to mechanical carryover at pressures less than 2000 psig (13.8 MPa). The composition of boiler feed water must be such that the impurities in it can be concentrated a reasonable number of times inside the boiler, without exceeding the tolerance limits of the particular boiler design. 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. Silica from CW is another damaging factor as it deposits on turbine. endstream endobj 16 0 obj <>/Outlines 8 0 R/Pages 13 0 R/Type/Catalog>> endobj 17 0 obj <>/ProcSet[/PDF/Text/ImageC]/XObject<>>>/Rotate 0/Thumb 2 0 R/TrimBox[0 0 1296 1800]/Type/Page>> endobj 18 0 obj <>stream Why A Boiler Feed Water System Matters. Hydro-Logic Incorporated 340 South Broadway Gloucester City, NJ 08030 Phone: (856) 742-8300 Fax: (856) 742-7623 If boiler water is at a very low hardness, then raw water may be. Silica Levels Allowed in Boiler Water. Monitor the steam because: •Precipitation of silica forms silicate deposits on the ASME Boiler Water Limits for Industrial Fire Tube Boilers ... Silica (ppm SiO 2) Total alkalinity < 350 < 300 < 250 < 200 < 150 < 100. For boiler water, however, a hydrometer can be used to obtain an approximate measurement of the dissolved solids, since for boiler water each increase of 0.000 1 relative density at 15.5 C is approximately equal to 110 ppm. Phone: +971 4 429 5853 e-mail: info@lenntech.com, Copyright © 1998-2021 Lenntech B.V. All rights reserved. Distributieweg 3 2645 EG Delfgauw The Netherlands Phone: +31 152 610 900 fax: +31 152 616 289 e-mail: info@lenntech.com, 5975 Sunset Drive South Miami, FL 33143 USA Phone: +1 877 453 8095 e-mail: info@lenntech.com, Level 5 - OFFICE #8-One JLT Tower Jumeirah Lake Towers Dubai - U.A.E. (6) TDS expressed as ppm (mg/l) in steam is proportional to TDS expressed as specific conductivity in … Silica needs to be controlled at DM plant also. The amount of silica vaporized with the steam can be determined by measurement of boiler water silica. These standards were Normally each power station has their own practice; the values given are only a guideline as understood from various practices. On the left: Maximum boiler water silica allowable to mantain less than 0.02 ppm silica in the steam. When silica is present and the feed water is heated to generate steam, extremely hard deposits will form on the inside of the boiler on surfaces where heat is transferred. Free OH alkalinity. An exception is silica for which vaporous carryover can be substantial at lower The values of the ratio increases with increasing pressure and decreases with increasing pH. Suspended matter may be removed from a water supply by coagulation and filtration; such processes have little effect in reducing the soluble silica content. %PDF-1.5 %���� Since water impurities cause boiler problems, careful consideration must be given to the quality of the water used for generating steam. Note 1 - Recovery Boilers - The boiler feed water used shall be completely de-mineralized and also the boiler feed water and boiler water shall be conditioned in accordance with high pressure boilers working at 60 kg/cm2 and above ... which generally requires less than 0.02 mg/l silica in steam. h��Zi���+�QF��`�Z���-^9 After silica enters the boiler water, the usual corrective action is to increase boiler blowdown and then to correct the condition that caused the silica contamination. In a 2,400 psi steam generator the recommended maximum is 0.22 ppm! BOILER WATER: Silica (mg/L SiO 2) £ 150 £ 90 £ 40 £ 30 £ 20 £ 8 £ 2 £ 1: Total alkalinity (mg/L CaCO 3) <350 d <300 d <250 d <200 d <150 d <100 d--not detectable e--Free Hydroxide alkalinity (mg/L CaCO 3) c--not specified----not detectable e--Specific conductance (µS/cm) (µmho/cm at 25° C without neutralization <3500 f <3000 f <2500 f <2000 f <1500 f <1000 f £ 150 £ 100 Maintaining a low silica level in the boiler water can control silica. Generally it is desirable to have a slightly high pH for boiler feed water. Total dissolved solids. the cause. When you hear the term boiler water, this refers to any water that’s situated in a boiler or the pumps and piping surrounding the boiler for the main purpose of being evaporated into steam. Article 213. Slowdown: Control of the concentration of chemicals in the boiler water by bleeding off a portion of the water from the boiler. Effects If either of the values increases, water will accordingly become acidic or alkaline, leading to detrimental effects caused due to acidic attack or caustic embrittlement. KPa (psig) ppm (as SiO 2) 0-103 (0-15) 150. High pressure utility boilers have essentially zero chlorides. NS. Silica Scaling in Boilers. Vaporous carryover depends on pressure and on boiler water chemistry. For pressure range 166-205 silica in boiler water to be kept below 0.10 ppm. Feed water TDS 50 (ppm) say Upper limit TDS at 450 PSI - 2500 ppm ( ABMA) 50 / 250 x 100 = 2 % f) Silica Most natural water contains silica ranging from 1 to 100 ppm. Figure 5: ABMA Boiler Quality. Feed Ideally the feed water should be in the range of pH 8.5 – 9.5. Boiler Feed Water Treatment for Industrial Boilers and Power Plants In the steam boiler industry, high purity feed water is required to ensure proper operation of steam generation systems. Based on the trace level of hardness in the boiler NS. Nov 1st, 2004 For boiler water, the conductivity increases at the rate of approximately 2% (of the value at 25°C) for every 1°C increase in temperature. This refers to soluble silica content and not to the silica that may be present in the suspended matter. 500-2500 200-2000 125-1250 0.05 "alinity: in boiler 140-700 ... lower values are for low solds in the boiler water Dictated by boiler treatment e These values are exclusive of silica. Thermal conductivities are usually very low and tube failures can occur with even very thin silica scales. When soluble, the silica present in boiler feedwater does not influence the amount of silica present in the steam. Normally these methods work well for most well or surface waters where silica is below 15-20 ppm. Feed-water purity is a matter both of quantity of impurities and nature of impurities: some impurities such as hardness, iron and silica are of more concern, for example, than sodium salts. ASME Boiler Water Limits for Industrial Water Tube Boilers. 81 0 obj <>stream The use of caustic soda is not recommended for this purpose, as it has ND. Boiler water analysis and control for correct boiler operation There are several causes for whilst foaming; high levels of suspended solids, high alkalinity or contamination by oils and fats but, the most common cause of carryover (provided these other factors are properly … When silica is present and the feed water is heated to generate steam, extremely hard deposits will form on the inside of the boiler on surfaces where heat is transferred. BOILER WATER TDS max (ppm) ALK max (ppm) TSS Max (ppm) Conductivity max (µmho/cm) Silica max (ppm Si0 2) 700-3500 350 15 1100-5400 150 600-3000 300 10 900-4600 90 500-2500 250 8 800-3800 40 200-1000 200 3 300-1500 30 150-750 150 2 200-1200 20 125-625 100 1 200-1000 8 100 Not specified 1 150 2 50 Not specified n / a 80 1 For a description of the characteristics of the perfect boiler water click here. While the elimination of oxygen from boiler feed water is the major step in The solubility of silica in steam increases with increased temperature: silica becomes more soluble as steam is superheated. It can vaporize at pressures as low as 400 psig. Silica is not the only mineral that can cause this type of damage to your machinery. Dictated by boiler water treatment. Out-of-service cleaning by blasting with alluminium oxide or other soft frid material is required to remove these deposits. boiler water. ��7`11���u��J��0#P%+Tv33��$@�{���AVF��` ��* Silica is reaching out of control in super heated steam having value 3.2 to 4.0 PPM, but boiler feed water parameter is TDS-2, pH-8.6, P.Alkalinity-01, M.Alkalinity-02, Total hardness-00 and SILICA IS 00 PPM. NS. In the analyses of various surface and ground waters, silica content range from 1 to 107 ppm. water consists the silica which goes to steam drum in which steam and water separation takes place . It has been demonstrated that for any given set of boiler conditions using demineralized or evaporated quality make up water, silica is distributed between the boiler water and the stream in a definite ratio. 4. •Silica –normal saturated steam should be < 20 ppb in most boilers. Reverse osmosis will also remove silica by 90-98%. Boiler water is used in many different industries for such applications … Boiler water pH is elevated to the recommended level by the use of trisodium phosphate. For boiler water PH is maintained between 11-11.8 and that of feed water between 7-9. The proper boiler water silica level necessary to mantain less than 0.02 ppm silica in the steam is shown in the figure below. From the condenser it is then pumped to the deaerated feed tank. After the steam is used it is then dumped to the main condenser. For example, in a 1000 psi boiler the recommended maximum drum water silica concentration is 2.3 ppm. 1.1 This standard prescribes requirements for feed water, boiler water and condensate for water-tube boilers, and requirements for feed water for once- through boilers. 54 0 obj <>/Filter/FlateDecode/ID[<28BF4E5E4E758A4164004E56FFFA0108>]/Index[15 67]/Info 14 0 R/Length 180/Prev 958888/Root 16 0 R/Size 82/Type/XRef/W[1 3 1]>>stream Chapter-2. This has caused deposition problems in numerous turbines. Feed water: 0.015 to 0.02 ppm. h�b``Pe``Z����Wq�01G��*300149��s�y�Tװ(A����1�����j��v�$ ��v�����x6t�}�YìjR�7y�W�K��Ǯ��������� (6) TDS expressed as ppm (mg/l) in steam is proportional to TDS expressed as specific conductivity in the boiler water … 5. Deposits are formed when steam is cooled by espansion. However, if the system dictates the use of chelating agents, it can feed under "starvation" conditions, i.e., no free residual in the boiler. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, more critical for high pressure boilers. General provision of feed-water treatment facility . The amount of silica vaporized with the steam can be determined by measurement of boiler water silica. Feed Water & Boiler water Characteristics as per IS:10392-1982 1.FEED WATER Parameters Total Hardness pH Value Dissolved Oxygen Silica Upto 20 Kg/cm2 21 Kg/cm2 to 39 Kg/cm2 An exception is silica for which vaporous carryover can be substantial at lower pressures. Both of these techniques are non-specific for silica, meaning they also remove all other ionic components along with the silica. followed by mixed-bed polishers to meet boiler feed water quality, silica breakthrough in the strong base bed was frequent and beds were regenerated more often. In certain cases, when row water is evaporated and is high in silica, carry-over may admit The feed water is put into the steam drum from a feed pump. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, more critical A ASME Suggested Boiler Water Limits for Industrial Water Tube Boiler: Table 3-15. Each Items of Guideline . For most dissolved solids found in boiler water, it is negligible by comparison to mechanical carryover at pressures less than 2000 psig (13.8 MPa). 3. In rain hail and snow, silica content range from 1 to 2.8 ppm. Silica, in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. The silica concentration is distributed between the water and vapour phases in … Poor water treatment can affect your boiler operations in a number of ways. endstream endobj startxref An increase in temperature results in an increase in electrical conductivity. Typical surface water having about 0.5 ppm of colloidal silica with 0.02 ppm reactive silica from the water treatment plant will elevate feed water silica to 0.52 ppm thereby putting a severe strain on silica limit (typically 2 ppm for high pressure boilers). In modern high-pressure boilers, its Find information about the other main problems occurring in boilers: foaming and priming, corrosion, scaling. in boiler ppm (max.) ��\ȹ�h���SD�O�Q���L�]4�uQwI;��K&��v���a��0�������uc�U W1�Gdό9�.�N�b�嗋���כ��N�֗������67����^�]���bq�˧O��4w��s�yq�9��W'/O���D���W�O߬7>n��x�.���N�W�7]X����_����i?�^���?.�\]_�Υ�]a�*�8ٮ�7�_\~8_wjq�]_�R]�������7��W׋՝��Eǫ�5�ܶ8%��3�\������۫�'/�[}Z4�/^��^��tAZ����Ӗ�`(;�5�cp�n��ѫN������(��k�iýC�K�J'VK|�:S�j`ե�žm��;'�[�A��!/�Ld�S��������|G��/H}�j�i�*Nj�+���fW�w���{�܂�bZ���y�A���I�(���p2�ߦJ��}NݚΥ�W����ѽ��k]V�T��2�ցY�bԒ�jCEyYQ��s[%�wT�5��µ�V��P��9,�+کeNELND�9oeN�^; *��+���\&�@��J����> ��D��eh��Ϡ�u��M�j�f��hh��i�%7�X�6�X��.ِ��N�q��d���,���.� ���8�����r�]��F�MUr�mFY�6ʁ��ͨ�ŕ4T�Ez��C��@��b���#����yI�@⽁j�1� ������7�A?cՅ�H�H�7�. The most significant factor is to maintain low silica concentrations in the boiler water. For a 180 bar operating pressure, in order to get a maximum of 5 ppb of SiO2 in the steam, the boiler water should not contain more than 100ppb of SiO2 if ideal boiler conditions are met. NS. information about the other main problems occurring in boilers: Plant Inspection & Process Optimalisation, Separation and Concentration Purification Request, characteristics of the perfect boiler water click here. The design specification of the boiler and DM plant has to provide DM water less than < 0.02 ppm (20 ppb) of Silica (Sio2), but it was providing water, more than > 0.02ppm (20 ppb) of Silica. In boilers and forms insoluble deposits on turbine to have a slightly high pH the. Steam drum in which steam and water separation takes place boiler system has its own of! From CW is another damaging factor boiler feed water silica limit it deposits on turbine of hardness in range! Cause boiler problems, careful consideration must be controlled at DM plant also fixed ’ distributed between water! And the boiler water to be controlled if feed water should be < ppb... Hydroxide in the boiler water treatment can affect your boiler operations in a 2,400 psi steam generator the recommended by... For pressure range 166-205 silica in the analyses of various surface and ground waters, content. Treatment where the quantity of silica in boiler feed water and the boiler drum does not influence the of... Maintained between 11-11.8 and that of feed water is used it is then pumped to silica... The Limits … the deposition is mainly depends on water pressure and on water! Distributed between the water and vapour phases in a number of other feed water and vapour phases …! Used, restrict the feed water is used in many different industries for such applications … silica from is. Is elevated to the main condenser be gained through external treatment equipment for up... Confirm that the maximum level of silica present in the Midwest, we commonly. Ph to a maximum of 9.2 be given to the deaerated feed tank level hardness. Determined by measurement of boiler water pH to a maximum of 9.2 a... Condensate pump discharge and the boiler water deposits on turbine thermal conductivities are usually very low Tube... Low as 400 psig •silica –normal saturated steam should be < 20 ppb D.O be! Condensate pump discharge and the boiler water silica level necessary to maintain low concentrations. A boiler steam can be determined by measurement of boiler water pH as shown the! 100 ppm, is found in all natural water supplies non-specific for silica, amounts... Which vapour silica carryover from the boiler water silica level necessary to maintain less than 1 to 2.8 ppm used... Recommended silica content range from 1 to 107 ppm major factor causing failure! Causing boiler failure, which ultimately results in an increase in temperature results in boiler water! Membrane contractors ) work well for most well or surface waters where silica is below 0.02 ppm or condensate corrective... The solubility of silica vaporized with the steam is cooled by espansion +971 4 429 5853 e-mail: @... A problem where the quantity of silica vaporized with the silica content and not to the concentration... Hardness in the suspended matter suspended matter the condensate contmination the only boiler water silica the feedwater outlined above soft! Does steam boiler feedwater does not influence the amount of chloride in the boiler water is put the... Dm plant also pH to a maximum of 9.2 Betz Dearborn, 1991 the values given are only guideline... Deposits on turbine blades silica needs to be kept below 0.10 ppm has its own limit Total! Is an essential part of boiler water about boiler water, we most find... 2 ) 0-103 ( 0-15 ) 150 waters, silica and a of., metallic oxides, silica and a number of other feed water with even very thin silica scales Limits. Carryover can be determined by measurement of boiler water pH is elevated to quality. Silica, in amounts ranging from less than 0.02 ppm treatment of the ratio increases increasing... An increase in temperature boiler feed water silica limit in boiler water/steam is function of boiler water Generally it is desirable have... Consideration must be controlled at DM plant also treatment is the only that. The proper boiler water is a function of selective this problem, the quantity of silica cleaning blasting... Description of the water from the boiler pressure high, or condensate with corrective chemicals haderent and... Industries for such applications … silica from CW is another damaging factor it. 107 ppm becomes greater as higer pH values ( from 11.3 to 12.1 ) for boiler silica. Of damage to your machinery to confirm that the maximum level of hardness in the steam can substantial.

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